Quantum-Dot-Sensitized Solar Cell with Unprecedentedly High Photocurrent
نویسندگان
چکیده
The reported photocurrent density (J(SC)) of PbS quantum dot (QD)-sensitized solar cell was less than 19 mA/cm(2) despite the capability to generate 38 mA/cm(2), which results from inefficient electron injection and fast charge recombination. Here, we report on a PbS:Hg QD-sensitized solar cell with an unprecedentedly high J(SC) of 30 mA/cm(2). By Hg(2+) doping into PbS, J(SC) is almost doubled with improved stability. Femtosecond transient study confirms that the improved J(SC) is due to enhanced electron injection and suppressed charge recombination. EXAFS reveals that Pb-S bond is reinforced and structural disorder is reduced by interstitially incorporated Hg(2+), which is responsible for the enhanced electron injection, suppressed recombination and stability. Thanks to the extremely high J(SC), power conversion efficiency of 5.6% is demonstrated at one sun illumination.
منابع مشابه
SILAR Sensitization as an Effective Method for Making Efficient Quantum Dot Sensitized Solar Cells
CdSe quantum dots were in situ deposited on various structures of TiO2 photoanode by successive ionic layer adsorption and reaction (SILAR). Various sensitized TiO2 structures were integrated as a photoanode in order to make quantum dot sensitized solar cells. High power conversion efficiency was obtained; 2.89 % (Voc=524 mV, Jsc=9.78 mA/cm2, FF=0.56) for the cells that sensitized by SILAR meth...
متن کاملRestricted charge recombination process in PbS quantum dot sensitized solar cells by different coating cycles of ZnS films
The relatively low power conversion efficiency (PCE) of quantum dot sensitized solar cells (QDSSCs) is attributed to charge recombination at the interfaces. Charge recombination process could be suppressed by coating the QD layer with a wide band gap semiconductor such as ZnS, which acts as a blocking layer between the QDs and hole transport material (HTM). In present study, to improve PCE of P...
متن کاملGiant photocurrent enhancement by transition metal doping in quantum dot sensitized solar cells
متن کامل
Preparation of CdIn2S4-CdS nanocomposite via a green route and using them in dot-sensitized solar cells for boosting efficiency
In this work In2S3 and CdS nanoparticles were prepared by a simple hydrothermal method and then annealed at 500 °C for 2 h in an Ar gas until CdIn2S4(CdIS)-CdS nanocomposites were formed. Afterwards, efficiency of the as-synthesized CdIS-CdS nanocomposite in quantum dot-sensitized solar cells (QDSSCs) was evaluated. For this purpose, the as-prepared CdIS-CdS nanocomposites were deposited on TiO...
متن کاملAn integrated approach to realizing high-performance liquid-junction quantum dot sensitized solar cells
Solution-processed semiconductor quantum dot solar cells offer a path towards both reduced fabrication cost and higher efficiency enabled by novel processes such as hot-electron extraction and carrier multiplication. Here we use a new class of low-cost, low-toxicity CuInSexS2-x quantum dots to demonstrate sensitized solar cells with certified efficiencies exceeding 5%. Among other material and ...
متن کامل